Ionic and Covalent Compound Help (page 2)
Ionic compounds are held together by strong ionic bonds. For example, when a metal reacts with a non-metal, an ionic compound forms. Ionic compounds are commonly hard crystalline solids with high melting points due to the strength of their ionic bonds. Ionic compounds serve as electrolytes (they conduct electricity), when dissolved in water to form solutions.
Naming Ionic Compounds
When naming an ionic compound, the first element gets the name root and the second adds on the ending “ ide .” The easiest example to remember is when sodium (Na) combines with chlorine (Cl) to form NaCl or sodium chlor ide . Other ionic compounds include calcium ox ide , lithium hydr ide , magnesium brom ide . ( Note : the metal cations are named first followed by the non-metal anions.)
When a chemist is trying to tell the difference between two ions of the same element, there are two ways to do it: the Stock system or the common naming system.
The first, the Stock system , invented by German Chemist Alfred Stock, at Cornell University, uses Roman numerals to show which ion is which. When referring to lead (Pb 2+ ) you would say “lead two” and write it Pb(II).
In the Stock system, FeCl 2 would be called iron(II) chloride, FeCl 3 would be iron(III) chloride, and PbBr 4 would be called lead(IV) bromide. The IUPAC naming system uses the Stock method.
Common Naming System
The second method or common naming system uses the endings (suffixes) to distinguish between chemical forms. If an experiment calls for cuprous sulfate, it is talking about a copper Cu + ion. The ending “ous” is used to name the lesser charged ion of the different copper forms. The copper ion Cu 2+ is known as a cupr ic ion, while Cu + is called the cupr ous ion, since it is the lesser charged ion of the two forms. The iron ion Fe 3+ is called a ferr ic ion, while Fe 2+ is known as a ferr ous ion.
Naming ionic compounds in chemistry is fairly simple when you remember to name the cation (+) first, followed by the anion (–). Writing formulas for ionic compounds is easy if you remember to keep the charges balanced. Then they almost name themselves.
In the compound MgCl 2 (magnesium chloride), one magnesium ion (Mg 2+ ) combines with two chloride ions (Cl − ). This combination makes the final molecule electrically neutral. It is written MgCl 2 . The subscript 2 attached to the chloride shows that 2 ions of negatively charged chlorine ions are needed to balance the formula.
Simple math is involved in writing formulas of polyatomic ions, but it is not rocket science. Just take one step at a time.
To find the lowest common multiple (LCM) , multiply each charge by whatever number works to give the least common multiple.
(Tip: lowest common multiple is easiest to use when the charge from one ion is used as the multiplier for the other ion.)
When writing the formula of gallium oxide, first write the element symbols, Ga 3+ and O 2− . The charges are dropped when you write this. Look at the LCM of 3 and 2 or 6. To get 6 Ga and 6 O, you multiply
2 (Ga 3+ ) + 3 (O 2− ) = 2 ( + 3) + 3( − 2) = 0
So the formula is written Ga 2 O 3 .
To write the formula for ammonium carbonate, (NH 4 ) 2 CO 3 , parentheses are used to show that two ions of ammonium are needed to balance one carbonate ion. ( Note: two NH 4 ions balance one ion.) Parentheses are used when writing the chemical formula of compounds of polyatomic ions. Parentheses are not needed unless a subscript is used. For the compound lead sulfate, PbSO 4 , only one ion of lead is used, so no parentheses are needed.
Remember, to name a compound from its formula, write the name of the positive ion (cation) first, followed by the name of the anion (negative ion). So Li 2 S is lithium sulfide.
In the case of some polyatomic ions, the naming of the different combining types can be remembered by checking the beginnings and endings of the element name. When there are only two types, the “ate” ending is used for the ion with more atoms. A sulfur atom may have four oxygen atoms around it (sulf ate ion, ) or three oxygen atoms (sulf ite ion, ). When four different types exist then the following rule applies:
- an ion with 4 other atoms is named: “per___ate”
- an ion with 3 other atoms is named: “___ate”
- an ion with 2 other atoms is named: “___ite”
- an ion with 1 other atom is named: “hypo___ite”
For polyatomic bromine ions, the naming would be per brom ate ( ), brom ate ( ), brom ite ( ), and hypobromite , (BrO 1− ). Figure 9.2 shows some clues to help with chemical naming.
The characteristics of different compounds are affected by their ionic character. It is easier to understand element bonding if you memorize or make flash cards to study these ionic forms and their types.
Not all compounds are ionic. When non-metals react with other non-metals, covalently bonded compounds form. Covalent compounds are generally soft solids with low melting points. Many are liquids or gases at room temperature. When only two elements are bonded, the compound is called a binary covalent compound .
To name a binary covalent compound, the IUPAC method orders the non-metals in a certain way. This order lists which non-metals to name first:
B > Si > C > P > N > H > S > I > Br > Cl > O > functional group
In a compound containing phosphorus and oxygen, phosphorus is named before oxygen.
For binary compounds, chemical naming includes writing the number of atoms of each type of element. These are given by a Greek prefix. Table 9.2 gives some Greek prefix tips to chemical naming.
To name a binary covalent compound, name the first non-metal, including its prefix, then name the second non-metal, using the prefix and changing the ending to “ide.” (Note: the prefix mono is generally not used for the first non-metal in the formula.)
Name the following compounds: CO, CO 2 , NO 2 , N 2 O 3 , CCl 4 , SF 6 . Did you get carbon monoxide, carbon dioxide, nitrogen dioxide, dinitrogen trioxide, carbon tetrachloride, and sulfur hexafluoride?
Practice problems for these concepts can be found at – Atomic Number and Ions Practice Test
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