Review the following concepts if needed:
Alcohols, Ethers, and Epoxides Practice Problems
Practice 1
Identify the products from reaction of (CH3)2C=O with- NaBD4 followed by H2O
- NaBD4 followed by CH3OD.
Solution 1
- (CH3)2CDOH
- (CH3)2CDOD.
In both reactions, nucleophilic : D– first attacks and reduces the carbonyl to form a basic alkoxide salt.
Practice 2
Prepare p–ClC6H4CHOHCH2CH3 from RCHO and R'MgX.Solution 2
Since the groups on the carbinol C are different, there are two combinations possible.
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