This is a great question for your son's teacher. Some teachers do maintain websites for their classes, and some include assignments and academic resources, such as spelling words.
If your son's school is located in the United States, you can get its contact information in SchoolFinder (if you don't already have it handy):
http://www.education.com/schoolfinder/
In addition to getting the spelling words from your son's teacher, you might also visit Education.com's Activities section to find fun ways to work with him on his reading and writing:
http://www.education.com/activity/ (Note: To find appropriate activities faster, be sure to select his grade in the right column of the page, and then the topic areas for reading and writing).
Education.com also offers Reading and Writing information centers:
http://www.education.com/topic/school-subject-reading/
http://www.education.com/topic/academic-subject-writing/
Hope all of the above resources are helpful to you.