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# Plastic Wrap Science Fair Project: Polymer Permeability

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### Problem

What type of plastic wrap is best at keeping the moisture inside a container?

### Materials

• Glad Wrap
• Handi-Wrap
• Saran Premium Wrap
• Mylar film
• Scissors
• 5 Identical cereal bowls
• Kitchen scale
• ½ cup measuring cup
• 2.5 cups of water
• Masking tape
• Marker
• Notebook
• Pencil

### Procedure

1. Get your cereal bowls ready by labeling them with masking tape. Label one “no wrap,” one “Glad,” one “Handi,” one “mylar lid,” one “mylar tape,” and one “Saran”.
2. Place half a cup of water in each bowl.
3. Cut squares of each plastic wrap large enough to wrap over the top of the bowl.
4. Tape each wrap around the bowl so that they’re all sealed. Leave the “no wrap” bowl without any kind of wrap.
5. Use your kitchen scale to weigh each bowl, and note the results in your notebook.
6. Now, put each bowl on the counter for a week. After a week, carefully weigh each bowl again.
7. Compare the results to the original weight, and divide the current weight by the original weight. Are they different?

### Results

Each bowl will lose moisture. The uncovered bowl will lose moisture faster than the others. Your results with the plastic wrap will vary. The taped mylar is less permeable, but its overall permeability will depend on how well you taped it!

### Why?

Remember the last time you brought home a helium balloon? It was a lovely sight sitting at the top of your room, until it gradually sank down to the floor. Why did it go flat? Gradually, the helium snuck through the pores in the plastic balloon and escaped into the rest of the room, so the balloon couldn't float anymore.

Different plastic wraps are made of different polymers, chains of molecules that have come together in a chemical reaction. These different polymers have different levels of permeability. Permeability is the ability to exchange a gas or a vapor through a solid surface. Even though the plastic looks solid, it still allows watermolecules to passthrough and evaporate.

Many plastic wraps used to be made out of polyvinylidene chloride, or PVdC. This plastic is less permeable than many plastic polymers and it clings well to other materials, forming a tight seal. However, due to concerns about the environmental impacts of the chloride and the health impacts of the phthalates used in this synthetic polymer, many companies have changed to low-density polyethylene (LDPE). LDPE is more permeable than PVdC. All of the brands you tried in this experiment are currently made of polyethylene plastics. These plastics are actually some of the most permeable polymers around! Mylar is made out of polyethylene terephthalate, often abbreviated as PET. This is a less permeable plastic, but as you could see, but doesn't cling like the other plastic wraps you used.

There are many factors that influence the way plastic wrap might keep something fresh. The thickness of the wrap will also change its permeability, and if two plastic wraps are made of the same polymer, the thicker wrap will be less permeable. The ability of a piece of wrap to cling tight can also help keep food from dehydrating, because moisture can move much more easily through cracks than it can through a solid surface.

### Going Further

How well do other containers such as Ziploc bags, glass jars, or reusable food containers with lids keep food fresh and moist? Can you design an experiment to compare these with plastic wrap?

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